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Highly Efficient and Selective Photooxidation of Sulfur Mustard Simulant by a Triazolobenzothiadiazole-Moiety-Functionalized Metal-Organic Framework in Air

TitleHighly Efficient and Selective Photooxidation of Sulfur Mustard Simulant by a Triazolobenzothiadiazole-Moiety-Functionalized Metal-Organic Framework in Air
Publication TypeJournal Article
Year of Publication2018
AuthorsZhang W.Q, Cheng K., Zhang H., Li Q.Y, Ma Z., Wang Z., Sheng J., Li Y., Zhao X., Wang X.J
JournalInorg Chem
Volume57
Issue8
Pagination4230-4233
Date PublishedApr 16
ISBN Number0020-1669 (Linking)
Accession Number29620354
Abstract

A photoactive triazolobenzothiadiazole (TBTD)-conjugated terphenyldicarboxylate (TPDC) linker was introduced into a porous and robust UiO-68 isoreticular zirconium metal-organic framework (denoted as UiO-68-TBTD) by the de novo synthetic approach of mixed TPDC struts. Under blue-light-emitting-diode irradiation, UiO-68-TBTD can serve as a heterogeneous photocatalyst for the highly efficient and selective oxidation of a sulfur mustard simulant (2-chloroethyl ethyl sulfide) to the corresponding much less toxic sulfoxide product, with a half-life of only 3 min in the open air atmosphere.

URLhttps://www.ncbi.nlm.nih.gov/pubmed/29620354
DOI10.1021/acs.inorgchem.8b00106
Short TitleHighly Efficient and Selective Photooxidation of Sulfur Mustard Simulant by a Triazolobenzothiadiazole-Moiety-Functionalized Metal-Organic Framework in Air

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